MATERIAL LIQUIDMIX

LIQUID

! ---------------------------------------------------------------------
! Non-evaporating species
! ---------------------------------------------------------------------
PC2H3CL(L)		PC2CL2(L)		PC2HCL(L)		PC2H2(L)
PC2H2CL2(L) 	PC2H4(L)		PC10H9CL(L)		PC10H10(L)
PC18H15CL(L)	PC18H16(L)		PC47H35CL(L)	PC47H36(L)

RCH(L)			RC2CL(L)		RC2H(L)			RC2H2CL(L)
RC2H3(L)		RC10H8CL(L)		RC10H9(L)		RC18H14CL(L)      
RC18H15(L)		RC47H34CL(L)	RC47H35(L)		RC53H34CL(L)
RC53H35(L)

H(L)			CL(L)

! Species representative of char
C24H12(L)       C24H11CL(L)

! ---------------------------------------------------------------------
! Evaporating species
! ---------------------------------------------------------------------
H2(L) 			CL2(L) 			HCL(L) 			C2H2(L)
C2H4(L) 		C6H6(L)         C8H8(L)		    C12H10(L)		
C14H10(L)       C6H5CL(L)		C11H9CL(L)		C15H11CL(L)
GASC(L) 

END


REACTIONS

                                           
! ************************************************************************************************************
! INITIATION REACTIONS FOR RADICAL DEHYROCHLORINATION PHENOMENON
! ************************************************************************************************************
! Weissman, M.; Benson, S.W.                     
! Pyrolysis of methyl chloride, a pathway in the chlorine-catalyzed polymerization of methane
! Int. J. Chem. Kinet. 16 307 (1984)             
!                                               
! Shilov, A.E.; Sabirova, R.D.                   
! Mechanism of the primary act of the thermal decomposition of methane derivatives
! Zh. Fiz. Khim. 6 1365 (1959)                   
!                                               
! Lim, K.PC2H3CL.; Michael, J.V.                 
! The thermal decomposition of CH3Cl using the Cl-atom absorption method and the bimolecular rate constant 
! for O + CH3 (1609-2002 K) with a pyrolysis photolysis-shock tube technique
! J. Chem. Phys. 98 3919-3928 (1993)             

PC2H3CL(L)=>RC2H3(L)+CL(L)                            .3430E+14   .000  54000.0
PC2CL2(L)=>RC2CL(L)+CL(L)                             .6430E+14   .000  58000.0
PC2HCL(L)=>RC2H(L)+CL(L)                              .3430E+14   .000  58000.0
PC2H2CL2(L)=>RC2H2CL(L)+CL(L)                         .6430E+14   .000  54000.0


! ************************************************************************************************************
! MOLECULAR DEHYDROCHLORINATION - RELATIVE LOW TEMPERATURES                      
! ************************************************************************************************************                                                                        
! Okada,K.;Tschuikow-Roux,E.;Evans,P.J.                                         
! Single-Pulse Shock-Tube Study of the Thermal Decomposition of Ethyl Fluoride and n-Propyl Chloride
! J.Phys.Chem. 84 467-471 (1980)                                                      
!                                                                                    
! Heydtmann, H.; Rinck, G.                                                            
! Die Kinetik des thermischen Zerfalls von 2-Chlorbutan in der H2phase                
! Z. Phys. Chem. (Neue Folge). 30 250-261 (1961)                                      
!                                                                                    
! Chuchani, G.; Hernandez, J.A.; Martin, I.                                           
! Neighboring olefinic double-bond participation in H2 phase pyrolysis of some alkenyl chlorides
! Int. J. Chem. Kinet. 11 1279-1286 (1979)                                            

PC2H3CL(L)=>PC2H2(L)+HCL(L)                           .5000E+13   .000  52000.0


! ************************************************************************************************************
! ABSTRACTION REACTIONS H OR CL                                                  
! ************************************************************************************************************                                                                     
! Arthur, N.L.; Bell, T.N.                                                            
! An evaluation of the kinetic data for hydrogen abstraction from silanes in the H2 phase
! Rev. Chem. Intermed. 2 37.00 -74.00 (1978)                                          
!                                                                                    
! Scherzer, K.; Loser, U.; Stiller, W.                                                
! BSBL-Rechnungen zu wasserstoffabspaltungsreaktionen durch alkenylradikale Vinylradikale
! Z. Chem. 27 300 (1987)                                                              
!                                                                                    
! Ahonkhai, S.I.; Lin, X-H.; Back, M.H.                                               
! Rate constants for abstraction of hydrogen from ethylene by methyl and ethyl radicals 
! relative to abstraction from propane and isobutane                                  
! Int. J. Chem. Kinet. 21 1.00 (1989)                                                 
!                                                                                    
! Knox, J.H.; Nelson, R.L.                                                            
! Competitive chlorination reactions in the H2 phase: hydrogen and C1-C5 saturated hydrocarbons
! Trans. Faraday Soc. 55 937 (1959)                                                   
!                                                                                    
! Pilgrim, J.S.; Taatjes, C.A.                                                        
! Infrared absorption probing of the Cl + C2H4 reaction: direct measurement of Arrhenius parameters for 
! hydrogen abstraction                                                 
! J. Phys. Chem. A: 101 4172-4177 (1997)                                              
!                                                                                    
! Szirovicza, L.; Marta, F.                                                           
! Some Reactions of the Isopropyl Radical                                             
! Int. J. Chem. Kinet.: 8 897 (1976)                                                   

PC2H3CL(L)+RC2H3(L)=>RC2H2CL(L)+PC2H4(L)              .4000E+12   .000  13500.0
PC2H4(L)+RC2H2CL(L)=>RC2H3(L)+PC2H3CL(L)              .4000E+12   .000  14500.0
PC2H3CL(L)+RCH(L)=>RC2H2CL(L)+0.5PC2H4(L)             .4000E+11   .000   4000.0
PC2H4(L)+RCH(L)=>RC2H3(L)+0.5PC2H4(L)                 .4000E+11   .000   4000.0

PC2H3CL(L)+RC2H(L)=>RC2H2CL(L)+PC2H2(L)               .4000E+11   .000   5000.0
PC2H4(L)+RC2CL(L)=>RC2H3(L)+PC2HCL(L)                 .4000E+11   .000   5000.0
PC2H3CL(L)+RC2CL(L)=>RC2H2CL(L)+PC2HCL(L)             .4000E+11   .000   5000.0
PC2H4(L)+RC2H(L)=>RC2H3(L)+PC2H2(L)                   .4000E+11   .000   5000.0

PC2H3CL(L)+CL(L)=>RC2H2CL(L)+HCL(L)                   .2400E+15   .000       .0
PC2H4(L)+CL(L)=>RC2H3(L)+HCL(L)                       .2400E+15   .000       .0

PC2H2(L)+RC2H2CL(L)=>RC2H(L)+PC2H3CL(L)               .4000E+12   .000  18500.0
PC2HCL(L)+RC2H2CL(L)=>RC2CL(L)+PC2H3CL(L)             .4000E+12   .000  18500.0
PC2H2(L)+RC2H3(L)=>RC2H(L)+PC2H4(L)                   .4000E+12   .000  17500.0
PC2HCL(L)+RC2H3(L)=>RC2CL(L)+PC2H4(L)                 .4000E+12   .000  17500.0
PC2H2(L)+RCH(L)=>RC2H(L)+0.5PC2H4(L)                  .4000E+12   .000  14500.0
PC2HCL(L)+RCH(L)=>RC2CL(L)+0.5PC2H4(L)                .4000E+12   .000  14500.0

PC2H2(L)+RC2CL(L)=>RC2H(L)+PC2HCL(L)                  .4000E+12   .000  14500.0
PC2HCL(L)+RC2H(L)=>RC2CL(L)+PC2H2(L)                  .4000E+12   .000  14500.0

PC2H2(L)+CL(L)=>RC2H(L)+HCL(L)                        .3000E+14   .000   6000.0
PC2HCL(L)+CL(L)=>RC2CL(L)+HCL(L)                      .3000E+14   .000   6000.0

PC2H3CL(L)+RC2H2CL(L)=>RC2H3(L)+PC2H2CL2(L)           .1000E+12   .000  17500.0
PC2H2CL2(L)+RC2H3(L)=>RC2H2CL(L)+PC2H3CL(L)           .1000E+12   .000  16500.0
PC2H3CL(L)+RCH(L)=>RC2H3(L)+0.5PC2H2CL2(L)            .1000E+13   .000  12000.0
PC2H2CL2(L)+RCH(L)=>RC2H2CL(L)+0.5PC2H2CL2(L)         .1000E+13   .000  12000.0

PC2H3CL(L)+RC2H(L)=>RC2H3(L)+PC2HCL(L)                .1000E+13   .000  12000.0
PC2H3CL(L)+RC2CL(L)=>RC2H3(L)+PC2CL2(L)               .1000E+13   .000  12000.0
PC2H2CL2(L)+RC2H(L)=>RC2H2CL(L)+PC2HCL(L)             .1000E+13   .000  12000.0
PC2H2CL2(L)+RC2CL(L)=>RC2H2CL(L)+PC2CL2(L)            .1000E+13   .000  12000.0

PC2HCL(L)+RC2H3(L)=>RC2H(L)+PC2H3CL(L)                .1000E+12   .000  21500.0
PC2CL2(L)+RC2H3(L)=>RC2CL(L)+PC2H3CL(L)               .1000E+12   .000  21500.0
PC2CL2(L)+RCH(L)=>RC2CL(L)+0.5PC2H2CL2(L)             .1000E+13   .000  17000.0
PC2HCL(L)+RCH(L)=>RC2H(L)+0.5PC2H2CL2(L)              .1000E+13   .000  17000.0
PC2HCL(L)+RC2H2CL(L)=>RC2H(L)+PC2H2CL2(L)             .1000E+12   .000  22500.0
PC2CL2(L)+RC2H2CL(L)=>RC2CL(L)+PC2H2CL2(L)            .1000E+12   .000  22500.0

PC2CL2(L)+RC2H(L)=>RC2CL(L)+PC2HCL(L)                 .1000E+13   .000  17000.0
PC2HCL(L)+RC2CL(L)=>RC2H(L)+PC2CL2(L)                 .1000E+13   .000  17000.0

RCH(L)+PC10H10(L)=>RC10H9(L)+0.5PC2H4(L)              .2000E+12   .000   9000.0
RCH(L)+PC18H16(L)=>RC18H15(L)+0.5PC2H4(L)             .3000E+12   .000   9000.0
RCH(L)+PC47H36(L)=>RC47H35(L)+0.5PC2H4(L)             .4000E+12   .000   6000.0
RC2H3(L)+PC10H10(L)=>RC10H9(L)+PC2H4(L)               .2000E+12   .000  15500.0
RC2H3(L)+PC18H16(L)=>RC18H15(L)+PC2H4(L)              .3000E+12   .000  14500.0
RC2H3(L)+PC47H36(L)=>RC47H35(L)+PC2H4(L)              .4000E+12   .000  12500.0
RC2H2CL(L)+PC10H10(L)=>RC10H9(L)+PC2H3CL(L)           .2000E+12   .000  16500.0
RC2H2CL(L)+PC18H16(L)=>RC18H15(L)+PC2H3CL(L)          .3000E+12   .000  15500.0
RC2H2CL(L)+PC47H36(L)=>RC47H35(L)+PC2H3CL(L)          .4000E+12   .000  13500.0
RC2H(L)+PC10H10(L)=>RC10H9(L)+PC2H2(L)                .2000E+12   .000   9000.0
RC2H(L)+PC18H16(L)=>RC18H15(L)+PC2H2(L)               .3000E+12   .000   9000.0
RC2H(L)+PC47H36(L)=>RC47H35(L)+PC2H2(L)               .4000E+12   .000   6000.0
RC2CL(L)+PC10H10(L)=>RC10H9(L)+PC2HCL(L)              .2000E+12   .000   9000.0
RC2CL(L)+PC18H16(L)=>RC18H15(L)+PC2HCL(L)             .3000E+12   .000   9000.0
RC2CL(L)+PC47H36(L)=>RC47H35(L)+PC2HCL(L)             .4000E+12   .000   6000.0

CL(L)+PC10H10(L)=>RC10H9(L)+HCL(L)                    .2000E+14   .000   5000.0
CL(L)+PC18H16(L)=>RC18H15(L)+HCL(L)                   .3000E+14   .000   4000.0
CL(L)+PC47H36(L)=>RC47H35(L)+HCL(L)                   .4000E+14   .000   4000.0


! ************************************************************************************************************
! BETA SCISSION REACTION ON C-CL BOND                                            
! ************************************************************************************************************                                                                        
! Barat, R.B.; Bozzelli, J.W.                                                         
! Kinetic and product distribution analysis of the reaction of atomic hydrogen with vinyl chloride
! J. Phys. Chem. 96 2494-2501 (1992)                                                  

RC2H2CL(L)=>PC2H2(L)+CL(L)                         	  .6000E+14   .000  19900.0


! ************************************************************************************************************
! BETA SCISSION REACTION ON C-C BOND                                             
! ************************************************************************************************************                                                                         
! Tsang, W.                                                                           
! Chemical kinetic data base for combustion chemistry. Part 4. Isobutane              
! J. Phys. Chem. Ref. Data 19 1.00-68.00 (1990)                                                 

RC2H3(L)=>0.5PC2H2(L)+RCH(L)+0.5H2(L)                 .3000E+14   .000  31000.0
RC2H2CL(L)=>RCH(L)+0.5PC2CL2(L)+0.5H2(L)              .3000E+14   .000  31000.0

! ************************************************************************************************************
! BETA SCISSION REACTION ON POLIY AROMATIC COMPOUNDS                             
! ************************************************************************************************************
! Derived from the previous kinetic rate parameters.

RC10H9(L)=>0.6C8H8(L)+0.11796C24H12(L)+RCH(L)+0.1833C2H4(L)+0.5C2H2(L)+0.02564H2(L)  	.1000E+14   .000  31000.0
RC18H15(L)=>C12H10(L)+RCH(L)+0.12490C24H12(L)+0.75C2H2(L)+0.25C2H4(L)  					.1000E+14   .000  31000.0
RC47H35(L)=>3C14H10(L)+RCH(L)+2C2H2(L)                									.1000E+14   .000  32000.0
RC53H35(L)=>1.6875C24H12(L)+RCH(L)+4.625C2H2(L)+1.125C2H4(L)  							.8000E+13   .000  33000.0


! ************************************************************************************************************
! MOLECULAR CONDENSATION (BIMOLECULAR)                                           
! ************************************************************************************************************                                                                        
! Lewis, D.K.; Bergmann, J.; Manjoney, R.; Paddock, R.; Kaira, B.L.                   
! Rates of reactions of cyclopropane, cyclobutane, cyclopentene, and cyclohexene in the presence of 
! boron trichloride                                                                   
! J. Phys. Chem. 88 4112 (1984) 

2PC2H2(L)=>0.3333C6H6(L)+0.1C2H2(L)+0.1666C6H6(L)+0.4PC2H2(L) 	  0.5000E+11   .000  25000.0
 USRPROG / HCL_CORR /

2PC2H2(L)=>0.4PC10H10(L)                       											.5000E+11   .000  26000.0
DUPLICATE
PC2H2(L)+PC10H10(L)=>0.66666PC18H16(L)+0.66666H2(L)   									.2000E+11   .000  27500.0
PC2H2(L)+PC18H16(L)=>0.4255PC47H36(L)+1.3404H2(L)     									.1000E+11   .000  27500.0
PC2H2(L)+PC47H36(L)=>2.04165C24H12(L)+6.7493H2(L)     									.1000E+11   .000  27500.0


! ************************************************************************************************************ 
! RADICAL CYCLO-ADDICTION (BIMOLECULAR)                                          
! ************************************************************************************************************ 

RCH(L)+PC2H2(L)=>0.2RC10H9(L)+0.8RCH(L)+0.00833C24H12(L)+0.15H2(L)  					.1000E+12   .000   6000.0
RCH(L)+PC10H10(L)=>0.5555RC18H15(L)+0.02314C24H12(L)+0.9722H2(L)+0.4444RCH(L)  			.1000E+12   .000   7000.0
RCH(L)+PC18H16(L)=>0.3829RC47H35(L)+0.617RCH(L)+0.01595C24H12(L)+1.3936H2(L)  			.1000E+12   .000   8000.0
RCH(L)+PC47H36(L)=>0.9038RC53H35(L)+0.09615RCH(L)+2.6346H2(L)  							.1000E+12   .000   9000.0
RC10H9(L)+PC10H10(L)=>RC18H15(L)+1.5H2(L)+0.08325C24H12(L)  							.1000E+12   .000   7000.0
RC10H9(L)+PC18H16(L)=>0.5744RC47H35(L)+0.4255RCH(L)+2.0904H2(L)+0.02393C24H12(L)  		.1000E+12   .000   8000.0
RC10H9(L)+PC47H36(L)=>RC53H35(L)+0.1666C24H12(L)+3.999H2(L)  							.1000E+12   .000   9000.0
RC18H15(L)+PC10H10(L)=>0.5744RC47H35(L)+0.4255RCH(L)+2.0904H2(L)+0.0239C24H12(L)  		.1000E+12   .000   8000.0
RC18H15(L)+PC18H16(L)=>0.66038RC53H35(L)+3.6085H2(L)+0.02745C24H12(L)+0.33962RCH(L)  	.1000E+12   .000   9000.0
RC18H15(L)+PC47H36(L)=>RC53H35(L)+0.4999C24H12(L)+5.0001H2(L)  							.1000E+12   .000   9000.0
PC2H2(L)+RC10H9(L)=>0.61111RC18H15(L)+0.3888RCH(L)+0.02546C24H12(L)+0.5694H2(L)  		.1000E+12   .000   7000.0
PC2H2(L)+RC18H15(L)=>0.41304RC47H35(L)+0.58696RCH(L)+0.9783H2(L)  						.1000E+12   .000   8000.0
PC2H2(L)+RC47H35(L)=>0.90566RC53H35(L)+0.09434RCH(L)+2.3773H2(L)+0.03773C24H12(L)  		.1000E+12   .000   9000.0


! ************************************************************************************************************
! TERMINATION - RADICAL RECOMBINATION                                            
! ************************************************************************************************************

RC2H3(L)+CL(L)=>PC2H3CL(L)                         					.5969E+12   .500   3324.0

CL(L)+CL(L)=>CL2(L)                                					.2500E+12   .000   1800.0
CL(L)+RC2H2CL(L)=>PC2H2CL2(L)                      					.1424E+12   .500   4121.0
CL(L)+RC2H(L)=>PC2HCL(L)                           					.1424E+12   .500   4121.0
CL(L)+RCH(L)=>0.5PC2H2CL2(L)                       					.1424E+12   .500   4121.0
CL(L)+RC2CL(L)=>PC2CL2(L)                          					.1424E+12   .500   4121.0
CL(L)+RC10H9(L)=>PC10H9CL(L)                       					.1550E+12   .500   3158.0
CL(L)+RC18H15(L)=>PC18H15CL(L)                     					.2083E+12   .500   3929.0
CL(L)+RC47H35(L)=>PC47H35CL(L)                     					.3354E+12   .500   5795.0
CL(L)+RC53H35(L)=>C24H11CL(L)+1.2083C24H12(L)+4.74996H2(L)  		.3550E+12   .500   6098.0

RC2CL(L)+RC10H9(L)=>0.03191H2(L)+0.2553PC47H35CL(L)+0.3723CL2(L)  	.4433E+11  1.000   5478.0
RC2CL(L)+RC18H15(L)=>0.4255PC47H35CL(L)+0.2872CL2(L)+0.05319H2(L)   .5932E+11  1.000   6250.0
RC2CL(L)+RC47H35(L)=>C24H11CL(L)+1.04166C24H12(L)+5.75H2(L)  		.9552E+11  1.000   8116.0
RC2CL(L)+RC53H35(L)=>C24H11CL(L)+1.29166C24H12(L)+4.25H2(L)  		.1011E+12  1.000   8419.0

RC10H9(L)+RC10H9(L)=>1.111PC18H16(L)+0.1111H2(L)      				.2422E+11  1.000   4516.0
RC10H9(L)+RC18H15(L)=>0.59574PC47H36(L)+1.27659H2(L)  				.6483E+11  1.000   5287.0
RC10H9(L)+RC47H35(L)=>2.375C24H12(L)+7.75H2(L)        				.1044E+12  1.000   7153.0
RC10H9(L)+RC53H35(L)=>2.625C24H12(L)+6.25H2(L)        				.1105E+12  1.000   7456.0
RC18H15(L)+RC18H15(L)=>1.5C24H12(L)+6H2(L)            				.4338E+11  1.000   6058.0
RC18H15(L)+RC47H35(L)=>2.7083C24H12(L)+8.75H2(L)      				.1397E+12  1.000   7924.0
RC18H15(L)+RC53H35(L)=>2.95833C24H12(L)+7.25H2(L)     				.1479E+12  1.000   8227.0

RC47H35(L)+RC47H35(L)=>3.9166C24H12(L)+11.5H2(L)     				.1125E+12  1.000   9790.0
RC47H35(L)+RC53H35(L)=>4.1666C24H12(L)+10H2(L)        				.2381E+12  1.000  10090.0

RC53H35(L)+RC53H35(L)=>4.4166C24H12(L)+8.5H2(L)       				.1260E+12  1.000  10040.0

RC2H3(L)+RC2H3(L)=>0.4PC10H10(L)+H2(L)                				.3563E+12  1.000   4848.0
RC2H3(L)+RC2H2CL(L)=>0.3CL2(L)+0.4PC10H9CL(L)+0.7H2(L)   			.3563E+12  1.000   4848.0
RC2H3(L)+RC2H(L)=>0.4PC10H10(L)                    					.1700E+12  1.000   5645.0
RC2H3(L)+RCH(L)=>0.3PC10H10(L)+0.5H2(L)               				.1700E+12  1.000   5645.0
RC2H3(L)+RC2CL(L)=>0.085106PC47H35CL(L)+0.4577CL2(L)+0.01063H2(L)  .1700E+12  1.000   5645.0

RC2H3(L)+RC10H9(L)=>0.6666670PC18H16(L)+0.6666670H2(L)  			.1858E+12  1.000   4682.0
RC2H3(L)+RC18H15(L)=>0.4255PC47H36(L)+1.3404H2(L)     				.2486E+12  1.000   5454.0
RC2H3(L)+RC47H35(L)=>2.04166C24H12(L)+6.75H2(L)      	 			.4004E+12  1.000   7319.0
RC2H3(L)+RC53H35(L)=>2.29167C24H12(L)+5.25H2(L)       				.4237E+12  1.000   7622.0

RC2H2CL(L)+RC2H2CL(L)=>0.4PC10H9CL(L)+0.8CL2(L)+0.2H2(L)  			.3563E+12  1.000   4848.0
RC2H2CL(L)+RC2H(L)=>0.45744CL2(L)+0.08510PC47H35CL(L)+0.0106H2(L)  	.1700E+12  1.000   5645.0
RC2H2CL(L)+RCH(L)=>0.35CL2(L)+0.3PC10H9CL(L)+0.15H2(L)   			.1700E+12  1.000   5645.0
RC2H2CL(L)+RC2CL(L)=>0.1666C24H11CL(L)+0.9166CL2(L)+0.0833H2(L)  	.1700E+12  1.000   5645.0

RC2H2CL(L)+RC10H9(L)=>0.6666PC18H15CL(L)+0.1666CL2(L)+0.5H2(L)  		.1858E+12  1.000   4682.0
RC2H2CL(L)+RC18H15(L)=>0.4255PC47H35CL(L)+0.28723CL2(L)+1.0531H2(L)  	.2486E+12  1.000   5454.0
RC2H2CL(L)+RC47H35(L)=>C24H11CL(L)+1.04165C24H12(L)+6.7493H2(L)  		.4004E+12  1.000   7319.0
RC2H2CL(L)+RC53H35(L)=>C24H11CL(L)+1.29166C24H12(L)+5.2499H2(L)  		.4237E+12  1.000   7622.0

RC2H(L)+RC2H(L)=>0.16666C24H12(L)                  		.2028E+11  1.000   6441.0
RC2H(L)+RCH(L)=>0.12488C24H12(L)+0.24995H2(L)         	.2028E+11  1.000   6441.0

RC2H(L)+RC10H9(L)=>0.5C24H12(L)+2H2(L)                	.4433E+11  1.000   5478.0
RC2H(L)+RC18H15(L)=>0.8333C24H12(L)+3H2(L)            	.5932E+11  1.000   6250.0
RC2H(L)+RC47H35(L)=>2.04166C24H12(L)+5.75H2(L)        	.9552E+11  1.000   8116.0
RC2H(L)+RC53H35(L)=>2.29166C24H12(L)+4.25H2(L)        	.1011E+12  1.000   8419.0


! ************************************************************************************************************
! ************************************************************************************************************
! CHLORINATED COMPOUNDS EVOLUTION
! ************************************************************************************************************
! ************************************************************************************************************
!                                                                               
! ************************************************************************************************************
! ABSTRACTION REACTION OF H FROM POLI CONDENSED CHLORINATED SYSTEMS              
! ************************************************************************************************************

RCH(L)+RCH(L)=>0.2PC10H10(L)                       	  .2028E+11  1.000   6441.0
RCH(L)+RC2CL(L)=>0.5PC2CL2(L)+0.08333C24H12(L)        .2028E+11  1.000   6441.0
RCH(L)+RC10H9(L)=>0.6111PC18H16(L)+0.1111H2(L)        .4433E+11  1.000   5478.0
RCH(L)+RC18H15(L)=>0.4042PC47H36(L)+0.7234H2(L)       .5932E+11  1.000   6250.0
RCH(L)+RC47H35(L)=>2C24H12(L)+6H2(L)                  .9552E+11  1.000   8116.0
RCH(L)+RC53H35(L)=>2.25C24H12(L)+4.5H2(L)             .1011E+12  1.000   8419.0
RCH(L)+PC10H9CL(L)=>RC10H8CL(L)+0.5PC2H4(L)           .2000E+12   .000   9000.0
RCH(L)+PC18H15CL(L)=>RC18H14CL(L)+0.5PC2H4(L)         .3000E+12   .000   9000.0
RCH(L)+PC47H35CL(L)=>RC47H34CL(L)+0.5PC2H4(L)         .4000E+12   .000   6000.0
RC2H3(L)+PC10H9CL(L)=>RC10H8CL(L)+PC2H4(L)            .2000E+12   .000  15500.0
RC2H3(L)+PC18H15CL(L)=>RC18H14CL(L)+PC2H4(L)          .3000E+12   .000  14500.0
RC2H3(L)+PC47H35CL(L)=>RC47H34CL(L)+PC2H4(L)          .4000E+12   .000  12500.0
RC2H2CL(L)+PC10H9CL(L)=>RC10H8CL(L)+PC2H3CL(L)        .2000E+12   .000  17500.0
RC2H2CL(L)+PC18H15CL(L)=>RC18H14CL(L)+PC2H3CL(L)      .3000E+12   .000  16500.0
RC2H2CL(L)+PC47H35CL(L)=>RC47H34CL(L)+PC2H3CL(L)      .4000E+12   .000  14500.0
RC2H(L)+PC10H9CL(L)=>RC10H8CL(L)+PC2H2(L)             .2000E+12   .000   9000.0
RC2H(L)+PC18H15CL(L)=>RC18H14CL(L)+PC2H2(L)           .3000E+12   .000   9000.0
RC2H(L)+PC47H35CL(L)=>RC47H34CL(L)+PC2H2(L)           .4000E+12   .000   6000.0
RC2CL(L)+PC10H9CL(L)=>RC10H8CL(L)+PC2HCL(L)           .2000E+12   .000   9000.0
RC2CL(L)+PC18H15CL(L)=>RC18H14CL(L)+PC2HCL(L)         .3000E+12   .000   9000.0
RC2CL(L)+PC47H35CL(L)=>RC47H34CL(L)+PC2HCL(L)         .4000E+12   .000   6000.0

CL(L)+PC10H9CL(L)=>RC10H8CL(L)+HCL(L)                 .2000E+14   .000   5000.0
CL(L)+PC18H15CL(L)=>RC18H14CL(L)+HCL(L)               .3000E+14   .000   4000.0
CL(L)+PC47H35CL(L)=>RC47H34CL(L)+HCL(L)               .5000E+14   .000   4000.0


! ************************************************************************************************************
! BETA SCISSION REACTION ON POLIY AROMATIC COMPC2H3CLOUNDS                       
! ************************************************************************************************************

RC10H8CL(L)=>C6H5CL(L)+0.5C2H2(L)+RCH(L)+.08333C24H12(L)  							.1000E+14   .000  31000.0
RC18H14CL(L)=>C11H9CL(L)+RCH(L)+0.16661C24H12(L)+C2H2(L)  							.1000E+14   .000  31000.0
RC47H34CL(L)=>C15H11CL(L)+1.125C24H12(L)+RCH(L)+0.5C2H2(L)+1.5C2H4(L)+0.75H2(L)  	.8000E+13   .000  31000.0

RC53H34CL(L)=>C24H11CL(L)+0.91666C24H12(L)+RCH(L)+0.5C2H2(L)+2.5C2H4(L)  			.2000E+13   .000  33000.0


! ************************************************************************************************************
! CHLORINATED LIGHT H2 EVOLUTION                                                 
! ************************************************************************************************************
! This reaction represent a pseudo transformation with production of chlorinated 
! compounds due to the dealkylation phenomenon in benzene DA condensation.             

PC2H2CL2(L)=>GASC(L)                           0.5000E+05   .000  25000.0
 USRPROG / HCL_CORR /

! ************************************************************************************************************
! MOLECULAR CONDENSATION-(BIMOLECULAR)                                           
! ************************************************************************************************************

PC2H2(L)+PC2HCL(L)=>0.5C6H5CL(L)+0.25CL2(L)+0.04166C24H12(L) 		    .5000E+11   .000  25000.0
 USRPROG / HCL_CORR /

PC2H2(L)+PC2HCL(L)=>0.2PC10H9CL(L)+0.0833C24H12(L)+0.4CL2(L)+0.1H2(L)  	.5000E+11   .000  26000.0
PC2H2(L)+PC10H9CL(L)=>0.66666PC18H15CL(L)+0.5H2(L)+0.16666CL2(L)  		.2000E+11   .000  27500.0
PC2HCL(L)+PC10H10(L)=>0.66666PC18H15CL(L)+0.5H2(L)+0.16666CL2(L)  		.2000E+11   .000  27500.0
PC2H2(L)+PC18H15CL(L)=>0.4255PC47H35CL(L)+1.05319H2(L)+0.28723CL2(L)  	.2000E+11   .000  27500.0
PC2HCL(L)+PC18H16(L)=>0.4255PC47H35CL(L)+1.05319H2(L)+0.28723CL2(L)  	.2000E+11   .000  27500.0
PC2H2(L)+PC47H35CL(L)=>C24H11CL(L)+1.04166C24H12(L)+6.75H2(L)  			.2000E+11   .000  27500.0
PC2HCL(L)+PC47H36(L)=>C24H11CL(L)+1.04166C24H12(L)+6.75H2(L)  			.2000E+11   .000  27500.0


! ************************************************************************************************************
! RADICAL CYCLO-ADDICTION (BIMOLECULAR)                                          
! ************************************************************************************************************

RCH(L)+PC2HCL(L)=>0.1RC10H8CL(L)+0.9RC2CL(L)+0.00833C24H12(L)+0.54995H2(L)  							.1000E+12   .000   6000.0
RCH(L)+PC10H9CL(L)=>0.5555RC18H14CL(L)+0.4444RCH(L)+0.75036H2(L)+0.22222CL2(L)+0.02314C24H12(L)  		.1000E+12   .000   7000.0
RC10H8CL(L)+PC10H10(L)=>RC18H14CL(L)+0.08333C24H12(L)+1.49998H2(L)  									.1000E+12   .000   7000.0
RC10H9(L)+PC10H9CL(L)=>RC18H14CL(L)+0.08333C24H12(L)+1.49998H2(L)  										.1000E+12   .000   7000.0
RCH(L)+PC18H15CL(L)=>0.38297RC47H34CL(L)+0.30851CL2(L)+0.617021RCH(L)+1.08506H2(L)+0.01595C24H12(L)  	.1000E+12   .000   8000.0
RC10H8CL(L)+PC18H16(L)=>0.42553RC47H34CL(L)+2.62234H2(L)+0.28723CL2(L)+0.57446RCH(L)+0.30939C24H12(L)  	.1000E+12   .000   8000.0
RC10H9(L)+PC18H15CL(L)=>0.57446RC47H34CL(L)+0.21277CL2(L)+0.42553RCH(L)+0.02393C24H12(L)+1.87767H2(L)  	.1000E+12   .000   8000.0
RC18H14CL(L)+PC10H10(L)=>0.42553RC47H34CL(L)+2.62234H2(L)+0.28723CL2(L)+0.57446RCH(L)+0.30939C24H12(L)  .1000E+12   .000   8000.0
RC18H15(L)+PC10H9CL(L)=>0.42553RC47H34CL(L)+2.62234H2(L)+0.28723CL2(L)+0.57446RCH(L)+0.30939C24H12(L)  	.1000E+12   .000   8000.0
RC18H14CL(L)+PC18H16(L)=>0.56603RC53H34CL(L)+0.21698CL2(L)+3.76907H2(L)+0.23191C24H12(L)+0.43396RCH(L)  .1000E+12   .000   9000.0
RC18H15(L)+PC18H15CL(L)=>0.66037RC53H34CL(L)+0.169811CL2(L)+0.33962RCH(L)+0.02752C24H12(L)+3.43881H2(L) .1000E+12   .000   9000.0
RC10H8CL(L)+PC47H36(L)=>RC53H34CL(L)+0.16661C24H12(L)+3.99998H2(L)  									.1000E+12   .000   9000.0
RC18H14CL(L)+PC47H36(L)=>RC53H34CL(L)+0.49995C24H12(L)+5.0H2(L)  										.1000E+12   .000   9000.0
RC10H8CL(L)+PC2H2(L)=>0.5RC18H14CL(L)+0.5RCH(L)+0.10418C24H12(L)+0.62495H2(L)+0.25CL2(L)  				.1000E+12   .000   7000.0
RC18H14CL(L)+PC2H2(L)=>0.4RC47H34CL(L)+0.3CL2(L)+0.6RCH(L)+0.02498C24H12(L)+0.74995H2(L)  				.1000E+12   .000   8000.0
RC10H9(L)+PC47H35CL(L)=>RC53H34CL(L)+0.16661C24H12(L)+3.99998H2(L)  									.1000E+12   .000   9000.0
RC18H15(L)+PC47H35CL(L)=>RC53H34CL(L)+0.49995C24H12(L)+5.0H2(L)  										.1000E+12   .000   9000.0
RCH(L)+PC47H35CL(L)=>0.9RC53H34CL(L)+0.1RCH(L)+0.05CL2(L)+2.59995H2(L)+0.00833C24H12(L)  				.1000E+12   .000   9000.0


! ************************************************************************************************************
!TERMINATION RADICAL RECOMBINATION                                              
! ************************************************************************************************************

RC10H9(L)+RC10H8CL(L)=>PC18H15CL(L)+0.0833C24H12(L)+0.5H2(L)  			.2422E+11  1.000   4516.0
RC10H9(L)+RC18H14CL(L)=>0.59574PC47H35CL(L)+0.20212CL2(L)+1.07446H2(L)  .6483E+11  1.000   5287.0
RC10H9(L)+RC47H34CL(L)=>C24H11CL(L)+1.375C24H12(L)+7.75H2(L)  			.1044E+12  1.000   7153.0
RC10H9(L)+RC53H34CL(L)=>C24H11CL(L)+1.6249C24H12(L)+6.25H2(L)  			.1105E+12  1.000   7456.0
RC18H15(L)+RC10H8CL(L)=>0.59574PC47H35CL(L)+0.20212CL2(L)+1.07446H2(L)  .6483E+11  1.000   5287.0
RC18H15(L)+RC18H14CL(L)=>C24H11CL(L)+0.5C24H12(L)+6H2(L)  				.4338E+11  1.000   6058.0
RC18H15(L)+RC47H34CL(L)=>C24H11CL(L)+1.7083C24H12(L)+8.75H2(L)  		.1397E+12  1.000   7924.0
RC18H15(L)+RC53H34CL(L)=>C24H11CL(L)+1.9583C24H12(L)+7.25H2(L)  		.1479E+12  1.000   8227.0
RC47H35(L)+RC10H8CL(L)=>C24H11CL(L)+1.375C24H12(L)+7.75H2(L)  			.1044E+12  1.000   7153.0
RC47H35(L)+RC18H14CL(L)=>C24H11CL(L)+1.7083C24H12(L)+8.75H2(L)  		.1397E+12  1.000   7924.0
RC47H35(L)+RC47H34CL(L)=>C24H11CL(L)+2.9166C24H12(L)+11.5H2(L)  		.1125E+12  1.000   9790.0
RC47H35(L)+RC53H34CL(L)=>C24H11CL(L)+3.1666C24H12(L)+9.9999H2(L)  		.2381E+12  1.000  10090.0
RC53H35(L)+RC10H8CL(L)=>C24H11CL(L)+1.62496C24H12(L)+6.24998H2(L)  		.1105E+12  1.000   7456.0
RC53H35(L)+RC18H14CL(L)=>C24H11CL(L)+1.95832C24H12(L)+7.25H2(L)  		.1479E+12  1.000   8227.0
RC53H35(L)+RC47H34CL(L)=>C24H11CL(L)+3.1666C24H12(L)+10H2(L)  			.2381E+12  1.000  10090.0
RC53H35(L)+RC53H34CL(L)=>C24H11CL(L)+3.41666C24H12(L)+8.5H2(L)  		.1260E+12  1.000  10040.0
RC10H8CL(L)+RC10H8CL(L)=>PC18H15CL(L)+0.0833C24H12(L)+0.5CL2(L)  		.2422E+11  1.000   4516.0
RC10H8CL(L)+RC18H14CL(L)=>0.5957PC47H35CL(L)+0.5744H2(L)+0.7021CL2(L)  	.6483E+11  1.000   5287.0
RC10H8CL(L)+RC47H34CL(L)=>2C24H11CL(L)+0.375C24H12(L)+7.75H2(L)  		.1044E+12  1.000   7153.0
RC10H8CL(L)+RC53H34CL(L)=>2C24H11CL(L)+0.625C24H12(L)+6.25H2(L)  		.1105E+12  1.000   7456.0
RC18H14CL(L)+RC18H14CL(L)=>1.5C24H11CL(L)+5.75H2(L)+0.25CL2(L)  		.4338E+11  1.000   6058.0
RC18H14CL(L)+RC47H34CL(L)=>2C24H11CL(L)+0.7083C24H12(L)+8.75H2(L)  		.1397E+12  1.000   7924.0
RC18H14CL(L)+RC53H34CL(L)=>2C24H11CL(L)+0.9583C24H12(L)+7.25H2(L)  		.1479E+12  1.000   8227.0
RC47H34CL(L)+RC47H34CL(L)=>2C24H11CL(L)+1.9166C24H12(L)+11.5H2(L)  		.1125E+12  1.000   9790.0
RC47H34CL(L)+RC53H34CL(L)=>2C24H11CL(L)+2.1666C24H12(L)+10H2(L)  		.2381E+12  1.000  10090.0
RC53H34CL(L)+RC53H34CL(L)=>2C24H11CL(L)+2.4166C24H12(L)+8.5H2(L)  		.1260E+12  1.000  10040.0

RC2H3(L)+RC10H8CL(L)=>0.6666PC18H15CL(L)+0.1666CL2(L)+0.5H2(L)  		.1858E+12  1.000   4682.0
RC2H3(L)+RC18H14CL(L)=>0.4255PC47H35CL(L)+0.2872CL2(L)+1.0531H2(L)  	.2486E+12  1.000   5454.0
RC2H3(L)+RC47H34CL(L)=>C24H11CL(L)+1.0416C24H12(L)+6.75H2(L)  			.4004E+12  1.000   7319.0
RC2H3(L)+RC53H34CL(L)=>C24H11CL(L)+1.29167C24H12(L)+5.25H2(L)  			.4237E+12  1.000   7622.0

CL(L)+RC10H8CL(L)=>0.4166C24H11CL(L)+1.7083H2(L)+0.7916CL2(L) 			.1556E+12   .500   3158.0
CL(L)+RC18H14CL(L)=>0.75C24H11CL(L)+2.875H2(L)+0.625CL2(L)  			.2083E+12   .500   3929.0
CL(L)+RC47H34CL(L)=>C24H11CL(L)+0.95833C24H12(L)+5.75H2(L)+0.5CL2(L)  	.3354E+12   .500   5795.0
CL(L)+RC53H34CL(L)=>C24H11CL(L)+1.20833C24H12(L)+4.25H2(L)+0.5CL2(L)  	.3550E+12   .500   6098.0

RC2H2CL(L)+RC10H8CL(L)=>0.6666PC18H15CL(L)+0.66667CL2(L)  				.1858E+12  1.000   4682.0
RC2H2CL(L)+RC18H14CL(L)=>0.4255PC47H35CL(L)+0.7872CL2(L)+0.5531H2(L)  	.2486E+12  1.000   5454.0
RC2H2CL(L)+RC47H34CL(L)=>2C24H11CL(L)+0.04166C24H12(L)+6.75H2(L)  		.4004E+12  1.000   7319.0
RC2H2CL(L)+RC53H34CL(L)=>2C24H11CL(L)+0.29167C24H12(L)+5.25H2(L)  		.4237E+12  1.000   7622.0

RC2H(L)+RC10H8CL(L)=>0.2553PC47H35CL(L)+0.3723CL2(L)+0.03191H2(L)  		.4433E+11  1.000   5478.0
RC2H(L)+RC18H14CL(L)=>0.4255PC47H35CL(L)+0.2872CL2(L)+0.0531H2(L)  		.5932E+11  1.000   6250.0
RC2H(L)+RC47H34CL(L)=>C24H11CL(L)+1.0416C24H12(L)+5.75H2(L)  			.9552E+11  1.000   8116.0
RC2H(L)+RC53H34CL(L)=>C24H11CL(L)+1.29167C24H12(L)+4.25H2(L)  			.1011E+12  1.000   8419.0
RCH(L)+RC10H8CL(L)=>0.4583C24H11CL(L)+0.2708CL2(L)+1.9791H2(L)  		.4433E+11  1.000   5478.0
RCH(L)+RC18H14CL(L)=>0.7916C24H11CL(L)+0.10416CL2(L)+3.1458H2(L) 		.5932E+11  1.000   6250.0
RCH(L)+RC47H34CL(L)=>C24H11CL(L)+C24H12(L)+6H2(L)        				.9552E+11  1.000   8116.0
RCH(L)+RC53H34CL(L)=>C24H11CL(L)+1.25C24H12(L)+4.5H2(L)  				.1011E+12  1.000   8419.0
RC2CL(L)+RC10H8CL(L)=>0.5C24H11CL(L)+0.75CL2(L)+1.25H2(L)  				.4433E+11  1.000   5478.0
RC2CL(L)+RC18H14CL(L)=>0.8333C24H11CL(L)+0.5833CL2(L)+2.4166H2(L)  		.5932E+11  1.000   6250.0
RC2CL(L)+RC47H34CL(L)=>2C24H11CL(L)+0.04166C24H12(L)+5.75H2(L)  		.9552E+11  1.000   8116.0
RC2CL(L)+RC53H34CL(L)=>2C24H11CL(L)+0.29166C24H12(L)+4.25H2(L)  		.1011E+12  1.000   8419.0


! ************************************************************************************************************
! MONO MOLECULAR RADICAL CYCLIZATION                                             
! ************************************************************************************************************
! Reaction proposed by Montaudo-Puglisi for benzene production-relevant only at  high temperature         
!                                                                                  
! Inizialization of dehydrochlorinated systems - derived from PE initialization reaction (+4000) 

PC2H2(L)=>2RCH(L)                               .1000E+15   .000  82000.0

!Mono molecular radical cyclization is related to two reactions: 
! + (RDS) primary radical formation                                                     
! + cyclization relatively faster                                                                                                                                      
!RC2H3>0.1666C6H6+RCH+0.5H2    			/1/13/0/31000/


! ************************************************************************************************************
! MOLECULAR CONDENSATION (MONO MOLECULAR)                                        
! ************************************************************************************************************

PC2H2(L)=>.2664C6H6(L)+0.2C2H2(L)                 					    .2000E+14   .000  40500.0
 USRPROG / HCL_CORR /

PC2H2(L)=>0.2PC10H10(L)                         						.2000E+14   .000  41500.0
 DUPLICATE
PC10H10(L)=>0.55555PC18H16(L)+0.55555H2(L)        						.1000E+13   .000  46500.0
PC18H16(L)=>0.38298PC47H36(L)+1.1064H2(L)          						.5000E+12   .000  48500.0
PC47H36(L)=>1.95829C24H12(L)+6.24983H2(L)          						.1000E+11   .000  52000.0
RC10H9(L)=>0.666C6H6(L)+RCH(L)+0.12499C24H12(L)+.25003H2(L)+C2H2(L)     .1000E+14   .000  31000.0
 USRPROG / HCL_CORR /

! ************************************************************************************************************
! RADICAL INTRAMOLECULAR CYCLIZATION (JULY 2002)                               
! ************************************************************************************************************

!RC10H9>.5RC18H15+.5RC+.02081C24H12+.37498H2	/6/15/0/29000

PC2H3CL(L)+CL(L)=>CL2(L)+RC2H3(L)				.4000E+13   .000  27000.0

!I1>CL+RC2H3    								/3.43/13/0/44000/                                                    
                                                                                  
!I1+RC2H3>RC2H2CL+PC2H4   						/4/8/0/13500/                                              
!I1+RCH>RC2H2CL+0.5PC2H4  						/4/8/0/10000/                                              
!I1+RC2H>RC2H2CL+PC2H2   						/4/8/0/3000/                                                
!I1+RC2CL>RC2H2CL+PC2HCL   						/4/8/0/3000/                                              
                                                                                    
!I1+CL>RC2H2CL+HCL   							/8/10/0/0/                                                      
                                                                                    
!I1+RC2H2CL>RC2H3+PC2H2CL2   					/1/8/0/16500/                                           
!I1+RCH>RC2H3+0.5PC2H2CL2  						/1/8/0/13000/                                             
!I1+RC2H>RC2H3+PC2HCL   						/1/9/0/10000/                                                
!I1+RC2CL>RC2H3+PC2CL2   						/1/9/0/10000/ 

                                                                                    
! ************************************************************************************************************
! HYDROGEN REACTIONS (JULY 2002)                                               
! ************************************************************************************************************
! ************************************************************************************************************
! BETA SCISSION REACTION ON C-H BOND                                             
! ************************************************************************************************************
   
RC2H3(L)=>PC2H2(L)+H(L)                            .2000E+14   .000  37000.0
RC2H2CL(L)=>PC2HCL(L)+H(L)                         .2000E+14   .000  37000.0

                                                                              
! ************************************************************************************************************
!ABSTRACTION REACTIONS H OR CL                                                  
! ************************************************************************************************************

H(L)+PC2H3CL(L)=>H2(L)+RC2H2CL(L)                     .6460E+13   .000   5210.0
H(L)+PC2H4(L)=>H2(L)+RC2H3(L)                         .6460E+13   .000   5210.0
!H(L)+PC2H2CL2(L)=>SPECIES TO BE DEFINED

!H(L)+PC2CL2(L)=>DOES NOT EXIST
H(L)+PC2HCL(L)=>H2(L)+RC2CL(L)                        .6460E+13   .000  10000.0
H(L)+PC2H2(L)=>H2(L)+RC2H(L)                          .6460E+13   .000  10000.0

H(L)+PC10H10(L)=>RC10H9(L)+H2(L)                      .6460E+13   .000  10000.0
 DUPLICATE
H(L)+PC18H16(L)=>RC18H15(L)+H2(L)                     .6460E+13   .000  10000.0
 DUPLICATE
H(L)+PC47H36(L)=>RC47H35(L)+H2(L)                     .6460E+13   .000  10000.0
 DUPLICATE

H(L)+PC10H9CL(L)=>RC10H8CL(L)+H2(L)                   .6460E+13   .000  10000.0
 DUPLICATE
H(L)+PC18H15CL(L)=>RC18H14CL(L)+H2(L)                 .6460E+13   .000  10000.0
 DUPLICATE
H(L)+PC47H35CL(L)=>RC47H34CL(L)+H2(L)                 .6460E+13   .000  10000.0
 DUPLICATE

!H(L)+PC2CL2(L)=>SPECIES TO BE DEFINED
H(L)+PC2HCL(L)=>RC2H2CL(L)                         	  .4710E+16   .000       .0
H(L)+PC2H2(L)=>RC2H3(L)                               .4710E+16   .000       .0

H(L)+PC10H10(L)=>RC10H9(L)+H2(L)                      .4710E+16   .000       .0
 DUPLICATE
H(L)+PC18H16(L)=>RC18H15(L)+H2(L)                     .4710E+16   .000       .0
 DUPLICATE
H(L)+PC47H36(L)=>RC47H35(L)+H2(L)                     .4710E+16   .000       .0
 DUPLICATE
 
H(L)+PC10H9CL(L)=>RC10H8CL(L)+H2(L)                   .4710E+16   .000       .0
 DUPLICATE
H(L)+PC18H15CL(L)=>RC18H14CL(L)+H2(L)                 .4710E+16   .000       .0
 DUPLICATE
H(L)+PC47H35CL(L)=>RC47H34CL(L)+H2(L)                 .4710E+16   .000       .0
 DUPLICATE
 
PC10H9CL(L)+H(L)=>C6H5CL(L)+0.5C2H2(L)+RCH(L)+.08333C24H12(L)+H2(L)  				.5780E+14   .000   8090.0
PC18H15CL(L)+H(L)=>C11H9CL(L)+RCH(L)+0.16661C24H12(L)+C2H2(L)+H2(L)  				.5780E+14   .000   8090.0
PC47H35CL(L)+H(L)=>C15H11CL(L)+1.125C24H12(L)+2.2510H2(L)+RCH(L)+2.0C2H2(L)+H2(L)  	.5780E+14   .000   8090.0

H(L)+RC2H3(L)=>PC2H4(L)                            .5969E+12   .500   3324.0
H(L)+CL(L)=>HCL(L)                                 .2500E+12   .000   1800.0
H(L)+RC2H2CL(L)=>PC2H3CL(L)                        .1424E+12   .500   4121.0
H(L)+RC2H(L)=>PC2H2(L)                             .1424E+12   .500   4121.0
H(L)+RCH(L)=>0.5PC2H4(L)                           .1424E+12   .500   4121.0
H(L)+RC2CL(L)=>PC2HCL(L)                           .1424E+12   .500   4121.0
H(L)+H(L)=>H2(L)                                   .1000E+14   .000   1000.0

! Terminations with aromatic radicals (-4- missing)

H(L)+RC10H9(L)=>PC10H10(L)                         .1550E+12   .500   3158.0
H(L)+RC18H15(L)=>PC18H16(L)                        .2083E+12   .500   3929.0
H(L)+RC47H35(L)=>PC47H36(L)                        .3354E+12   .500   5795.0

H(L)+RC10H8CL(L)=>PC10H9CL(L)                      .1550E+12   .500   3158.0
H(L)+RC18H14CL(L)=>PC18H15CL(L)                    .2083E+12   .500   3929.0
H(L)+RC47H34CL(L)=>PC47H35CL(L)                    .3354E+12   .500   5795.0


END
